Blondie: 'Atomic'
Game: GTA : Vice City
Ok, so this song itself is not from a video game, but Debbie Harry is one of many stars to have graced their voice talent to the Grand Theft Auto series. Debborah plays the voice of the taxi controller in GTA : Vice City. Go see the entire list here (featuring Axl Rose, Samuel L. Jackson, Kyle MacLachlan, Burt Reynolds and, er, Phil Collins.)